Blue-to-Green Emitting Neutral Ir(III) Complexes Bearing Pentafluorosulfanyl Groups: A Combined Experimental and Theoretical Study.

ABSTRACT: A structure-property relationship study of neutral heteroleptic (1 and 2, [Ir(C^∧N)₂(L^∧X)]) and homoleptic (3 and 4, fac-[Ir(C^∧N)₃]) Ir(III) complexes (where L^∧X = anionic 2,2,6,6-tetramethylheptane-3,5-dionato-κO³,κO⁶ (thd) and C^∧N = a cyclometalating ligand bearing a pentafluorosulfanyl (-SF₅) electron-withdrawing group (EWG) at the C₄ (HL1) and C₃ (HL2) positions of the phenyl moiety) is presented. These complexes have been fully structurally characterized, including by single-crystal X-ray diffraction, and their electrochemical and optical properties have also been extensively studied. While complexes 1 ([Ir(L1)₂(thd)]), 3 (Ir(L1)₃), a

SUBMITTER: Pal AK 

PROVIDER: S-EPMC5499099 | biostudies-literature | 2017 Jul

REPOSITORIES: biostudies-literature