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Bis(N'-{(E)-[(2E)-1,3-di-phenyl-prop-2-en-1-yl-idene]amino}-N-ethyl-carbamimido-thio-ato-κ²N',S)zinc(II): crystal structure and Hirshfeld surface analysis.

ABSTRACT: The title Zn^II complex, [Zn(C₁₈H₁₈N₃S)₂], (I), features two independent but chemically equivalent mol-ecules in the asymmetric unit. In each, the thio-semicarbazonate monoanion coordinates the Zn^II atom via the thiol-ate-S and imine-N atoms, with the resulting N₂S₂ donor set defining a distorted tetra-hedral geometry. The five-membered ZnSCN₂ chelate rings adopt distinct conformations in each independent mol-ecule, i.e. one ring is almost planar while the other is twisted about the Zn-S bond. In the crystal, the two mol-ecules comprising the asymmetric unit are linked by amine-N-H⋯N(imine) and amine-N-H⋯S(thiol-ate) hydrogen bonds via an eight-membered heterosynthon, {⋯HN

SUBMITTER: Tan MY

PROVIDER: S-EPMC5499278 | biostudies-literature | 2017 Jul

REPOSITORIES: biostudies-literature

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Bis(N'-{(E)-[(2E)-1,3-di-phenyl-prop-2-en-1-yl-idene]amino}-N-ethyl-carbamimido-thio-ato-κ²N',S)zinc(II): crystal structure and Hirshfeld surface analysis.

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Dataset Information

Bis(N'-{(E)-[(2E)-1,3-di-phenyl-prop-2-en-1-yl-idene]amino}-N-ethyl-carbamimido-thio-ato-κ2N',S)zinc(II): crystal structure and Hirshfeld surface analysis.

OmicsDI is part of the ELIXIR infrastructure

Tweets

Bis(N'-{(E)-[(2E)-1,3-di-phenyl-prop-2-en-1-yl-idene]amino}-N-ethyl-carbamimido-thio-ato-κ²N',S)zinc(II): crystal structure and Hirshfeld surface analysis.