Unknown

Dataset Information

0

Crystal structure of bis-[tetra-kis-(tetra-hydro-furan-?O)lithium] bis[?-2,2',2''-methanetriyltris(4,6-di-tert-butylphenolato)-?4O,O':O',O'']-dimagnesiate.

ABSTRACT: The title ion-association metal complex, [Li(C4H8O)4]2[Mg2(C43H61O3)2], has been synthesized from the tridentate phenolic ligand tris-(3,5-di-tert-butyl-2-hy-droxy-phen-yl)methane in tetra-hydro-furan (THF). The aryl-oxo magnesiate complex anion is binuclear with each Mg2O4 complex unit inversion-related and bridged through the two tridentate chelating phenolate O-donors of the ligand. The complex centres have a distorted tetra-hedral stereochemistry [Mg-O range 1.8796?(17)-2.0005?(16)?Å] and an Mg?Mg separation of 2.9430?(14)?Å]. The LiO4 coodination sphere of the cation comprises four THF O-donor atoms and has a slightly distorted tetra-hedral conformation [Li-O range 1.899?(5)- 1.953?(5)?Å]. In the crystal, a number of stabilizing intra-anion C-H?O hydrogen-bonding inter-actions are present but no inter-species associations are found.

SUBMITTER: Zhou H 

PROVIDER: S-EPMC5499282 | biostudies-literature | 2017 Jul

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Crystal structure of bis-[tetra-kis-(tetra-hydro-furan-κ<i>O</i>)lithium] bis[μ-2,2',2''-methanetriyltris(4,6-di-<i>tert</i>-butylphenolato)-κ<sup>4</sup><i>O</i>,<i>O</i>':<i>O</i>',<i>O</i>'']-dimagnesiate.

Zhou Hongyan H   Wang Lei L  

Acta crystallographica. Section E, Crystallographic communications 20170613 Pt 7

The title ion-association metal complex, [Li(C<sub>4</sub>H<sub>8</sub>O)<sub>4</sub>]<sub>2</sub>[Mg<sub>2</sub>(C<sub>43</sub>H<sub>61</sub>O<sub>3</sub>)<sub>2</sub>], has been synthesized from the tridentate phenolic ligand tris-(3,5-di-<i>tert</i>-butyl-2-hy-droxy-phen-yl)methane in tetra-hydro-furan (THF). The aryl-oxo magnesiate complex anion is binuclear with each Mg<sub>2</sub>O<sub>4</sub> complex unit inversion-related and bridged through the two tridentate chelating phenolate O-donor  ...[more]

Similar Datasets

Unknown Tetra-kis(μ-acetato-κ<sup>2</sup><i>O</i>:<i>O</i>')bis-[(tetra-hydro-furan-κ<i>O</i>)chromium(II)].
| S-EPMC10561221 | biostudies-literature
Unknown Crystal structure of bromido-penta-kis-(tetra-hydro-furan-κ<i>O</i>)magnesium bis-[1,2-bis-(di-phenyl-phosphan-yl)benzene-κ<sup>2</sup> <i>P</i>,<i>P</i>']cobaltate(-1) tetra-hydro-furan disolvate.
| S-EPMC6362642 | biostudies-literature
Unknown Tetra-kis(μ-penta-fluoro-benzoato-κO:O')bis-[(tetra-hydro-furan-κO)molybdenum(II)].
| S-EPMC3200930 | biostudies-literature
Unknown (1,4,7,10,13,16-Hexaoxa-cyclo-octa-decane-κ(6) O)bis-(tetra-hydro-furan-κO)potassium bis-[(1,2,3,4-η)-anthracene]cobalt(-I) tetra-hydro-furan monosolvate.
| S-EPMC3914043 | biostudies-literature
Unknown Diaqua-bis-(1,10-phenanthroline)nickel(II) tetra-kis-(cyanido-κC)nickelate(II) tetra-hydro-furan solvate monohydrate.
| S-EPMC2983352 | biostudies-literature
Unknown Crystal structure of tetra-kis-(tetra-hydro-furan-κO)bis-(tri-fluoro-methane-sulfonato-κO)iron(II).
| S-EPMC6775732 | biostudies-literature
Unknown Bis(μ-2-{bis-[(2-oxidobenzyl-idene)amino]-meth-yl}phenolato)bis-[(tetra-hydro-furan)-samarium(III)] tetra-hydro-furan disolvate.
| S-EPMC3344343 | biostudies-literature
Unknown Crystal structure of an unknown tetra-hydro-furan solvate of tetra-kis-(μ 3-cyanato-κ(3) N:N:N)tetra-kis-[(triphenyl-phosphane-κP)-silver(I)].
| S-EPMC4647345 | biostudies-literature
Unknown Crystal structures and Hirshfeld surface analyses of tetra-kis-(4,5-di-hydro-furan-2-yl)silane and tetra-kis-(4,5-di-hydro-furan-2-yl)germane.
| S-EPMC10162092 | biostudies-literature
Unknown Tetra-kis[μ-N,N'-bis-(4-bromo-phen-yl)formamidinato-κN:N']dimolyb-denum(II) tetra-hydro-furan solvate.
| S-EPMC3099865 | biostudies-literature