Graphene related magnetic materials: micromechanical exfoliation of 2D layered magnets based on bimetallic anilate complexes with inserted [Fe^III(acac₂-trien)]⁺ and [Fe^III(sal₂-trien)]⁺ molecules.

ABSTRACT: The syntheses, structures and magnetic properties of the coordination compounds of formula [Fe^III(acac₂-trien)][Mn^IICr^III(Cl₂ An)₃]·(CH₃CN)₂ (1), [Fe^III(acac₂-trien)][Mn^IICr^III(Br₂An)₃]·(CH₃CN)₂ (2) and [Ga^III(acac₂-trien)][Mn^IICr^III(Br₂An)₃]·(CH₃CN)₂ (3) are reported. They exhibit a 2D anionic network formed by Mn(ii) and Cr(iii) ions linked through anilate ligands, while the [Fe^III(acac₂-trien)]⁺ or [Ga^III(acac₂-trien)]⁺ charge-compensating ca

SUBMITTER: Abherve A 

PROVIDER: S-EPMC5500854 | biostudies-literature | 2015 Aug

REPOSITORIES: biostudies-literature