Redox-promoted associative assembly of metal-organic materials.

ABSTRACT: We develop an associative synthesis of metal-organic materials that combines solid-state metal oxidation and coordination-driven self-assembly into a one-step, waste-free transformation. The methodology hinges on the unique reactivity of ortho-quinones, which we introduce as versatile oxidants for mechanochemical synthesis. Our strategy opens a previously unexplored route to paramagnetic metal-organic materials from elementary metals.

SUBMITTER: Glavinovic M 

PROVIDER: S-EPMC5530005 | biostudies-literature | 2016 Jan

REPOSITORIES: biostudies-literature