Metathesis Activity Encoded in the Metallacyclobutane Carbon-13 NMR Chemical Shift Tensors.

ABSTRACT: Metallacyclobutanes are an important class of organometallic intermediates, due to their role in olefin metathesis. They can have either planar or puckered rings associated with characteristic chemical and physical properties. Metathesis active metallacyclobutanes have short M-C_α/α' and M···C_β distances, long C_α/α'-C_β bond length, and isotropic ¹³C chemical shifts for both early d⁰ and late d⁴ transition metal compounds for the α- and β-carbons appearing at ca. 100 and 0 ppm, respectively. Metallacyclobutanes that do not show metathesis activity have ¹³C chemical shifts of the α- and β-carbons at typically 40 and 30 ppm, respectively, for d⁰ systems, with upfield shifts to ca. -30 ppm for the

SUBMITTER: Gordon CP 

PROVIDER: S-EPMC5532720 | biostudies-literature | 2017 Jul

REPOSITORIES: biostudies-literature