Interplay between Terminal and Bridging Diiron Hydrides in Neutral and Oxidized States.

ABSTRACT: This study describes the structural, spectroscopic, and electrochemical properties of electronically unsymmetrical diiron hydrides. The terminal hydride Cp*Fe(pdt)Fe(dppe)(CO)H ([1(t-H)]⁰, Cp*^- = Me₅C₅^-, pdt^2- = CH₂(CH₂S^-)₂, dppe = Ph₂PC₂H₄PPh₂) was prepared by hydride reduction of [Cp*Fe(pdt)Fe(dppe)(CO)(NCMe)]⁺. As established by X-ray crystallography, [1(t-H)]⁰ features a terminal hydride ligand. Unlike previous examples of terminal diiron hydrides, [1(t-H)]⁰ does not isomerize to the bridging hydride [1(μ-H)]⁰. Oxidation of [1(

SUBMITTER: Yu X 

PROVIDER: S-EPMC5538148 | biostudies-literature | 2017 Jun

REPOSITORIES: biostudies-literature