Enantiomerically enriched tris(boronates): readily accessible conjunctive reagents for asymmetric synthesis.

ABSTRACT: The catalytic enantioselective diboration of vinyl boronate esters furnishes chiral tris(boronates) in a selective fashion. Subsequent deborylative alkylation occurs in a diastereoselective fashion, both for intermolecular and intramolecular processes.

SUBMITTER: Coombs JR 

PROVIDER: S-EPMC5539535 | biostudies-literature | 2014 Nov

REPOSITORIES: biostudies-literature