Design and reactions of a carbon Lewis base/boron Lewis acid frustrated Lewis pair.

ABSTRACT: The conjugated dienamine 4 selectively adds Piers' borane [HB(C6F5)2] to give the enamine/borane system 5, which features a boratirane structure by internal enamine carbon Lewis base to boron Lewis acid interaction. Compound 5 behaves as a C/B frustrated Lewis pair and undergoes typical addition reactions to benzaldehyde, several nitriles and to sulfur dioxide.This article is part of the themed issue 'Frustrated Lewis pair chemistry'.

SUBMITTER: Moricke J 

PROVIDER: S-EPMC5540844 | biostudies-literature | 2017 Aug

REPOSITORIES: biostudies-literature