Platinum Nanoparticle-embedded Porous Diamond Spherical Particles as an Active and Stable Heterogeneous Catalyst.

ABSTRACT: Platinum nanoparticle-embedded porous diamond spherical particles (PtNP@PDSPs), as an active and stable catalyst, were fabricated by spray-drying of an aqueous slurry containing nanodiamond (ND) particles, platinum nanoparticles (PtNP), and polyethylene glycol (PEG) to form ND/PtNP/PEG composite spherical particles, followed by removal of PEG and a short-time diamond growth on the surface. The average diameter of the PtNP@PDSPs can be controlled in the range of 1-5 μm according to the spray-drying conditions. The Brunauer-Emmett-Teller (BET) surface area and average pore diameter of the PtNP@PDSPs were estimated to be ca. 170-300 m² g^-1 and ca. 4-13 nm, respectively. When ND with the size of 20-30 nm was used, the size of PtNP in the PtNP@PDSP was almost unchanged at

SUBMITTER: Kondo T 

PROVIDER: S-EPMC5561195 | biostudies-literature | 2017 Aug

REPOSITORIES: biostudies-literature