Tunable two-dimensional interfacial coupling in molecular heterostructures.

ABSTRACT: Two-dimensional van der Waals heterostructures are of considerable interest for the next generation nanoelectronics because of their unique interlayer coupling and optoelectronic properties. Here, we report a modified Langmuir-Blodgett method to organize two-dimensional molecular charge transfer crystals into arbitrarily and vertically stacked heterostructures, consisting of bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF)/C₆₀ and poly(3-dodecylthiophene-2,5-diyl) (P3DDT)/C₆₀ nanosheets. A strong and anisotropic interfacial coupling between the charge transfer pairs is demonstrated. The van der Waals heterostructures exhibit pressure dependent sensitivity with a high piezoresistance coefficient of -4.4 × 10^-6 Pa^-1, and conductance and capacitance

SUBMITTER: Xu B 

PROVIDER: S-EPMC5567094 | biostudies-literature | 2017 Aug

REPOSITORIES: biostudies-literature