Seed-mediated synthesis and SERS performance of graphene oxide-wrapped Ag nanomushroom.

ABSTRACT: A facile seed-mediated method was developed to modify core-shell Ag nanosphere@PSPAA with another Ag layer for achieving an enhancement of their surface-enhanced Raman scattering (SERS) activity. Interestingly, an Ag bridge in the polymer shell connected the inner and outer Ag layers, resulting in a mushroom-like nanostructure. The outer Ag grew around the polymer shell to form the cap of the nanomushrooms (NMs) with the extension of the reaction time. The epitaxial growth mechanism of this novel nanostructure was investigated by tuning the type of seed from nanosphere to nanocube and nanorod. With the growth of the outer Ag cap, the SERS intensity of these Ag NMs increased significantly together with the red-shifting and broadening of their typical localized surface plasmon resonance band

SUBMITTER: Jiang T 

PROVIDER: S-EPMC5574994 | biostudies-literature | 2017 Aug

REPOSITORIES: biostudies-literature