Oxidative [1,2]-Brook Rearrangements Exploiting Single-Electron Transfer: Photoredox-Catalyzed Alkylations and Arylations.

ABSTRACT: Oxidative [1,2]-Brook rearrangements via hypervalent silicon intermediates induced by photoredox-catalyzed single-electron transfer have been achieved, permitting the formation of reactive radical species that can engage in alkylations and arylations.

SUBMITTER: Deng Y 

PROVIDER: S-EPMC5575796 | biostudies-literature | 2017 Jul

REPOSITORIES: biostudies-literature