Strategies for the Construction of Supramolecular Dimers versus Homoleptic 1D Coordination Polymers Starting from the Diphosphorus [Cp₂Mo₂(CO)₄(η²-P₂)] Complex and Silver(I) Salts.

ABSTRACT: The reactions of the tetrahedral diphosphorus [Cp₂Mo₂(CO)₄(η²-P₂)] (1; Cp = C₅H₅) complex with Ag[Al{OC(CF₃)₃}₄] (AgTEF) (A) and Ag[FAl{OC(C₆F₅)(C₆F₁₀)}₃] (AgFAl) (B) were studied. The first reaction led to the formation of the [Ag₂(η²-1)₂(η¹:η¹-1)₂][TEF]₂ (2) dimer and the [Ag₂(η¹:η¹-1)₃] _n [TEF]_2n (3) coordination polymer, whereas the second reaction afforded the [Ag₂(η¹:η¹-1)<

SUBMITTER: Elsayed Moussa M 

PROVIDER: S-EPMC5586200 | biostudies-literature | 2017 Jul

REPOSITORIES: biostudies-literature