Crystal structure and Hirshfeld surface analysis of aqua-bis-(nicotinamide-κN¹)bis-(2,4,6-tri-methyl-benzoato-κO)zinc.

ABSTRACT: The asymmetric unit of the title complex, [Zn(C₁₀H₁₁O₂)₂(C₆H₆N₂O)₂(H₂O)], contains one half of the complex mol-ecule, and the Zn^II cation and the water O atom lie on a twofold rotation axis. The Zn^II cation is coordinated by two carboxyl-ate O atoms of the two symmetry-related 2,4,6-tri-methyl-benzoate (TMB) anions and by the water O atom at distances of 2.0311 (16) and 2.076 (2) Å to form a slightly distorted trigonal-planar arrangement, while the distorted trigonal-bipyramidal coordination sphere is completed by the two pyridine N atoms of the two symmetry-related monodentate nicotinamide (NA) ligands at distances of 2.2066 (19) Å in the axial positions. In the crystal

SUBMITTER: Hokelek T 

PROVIDER: S-EPMC5588578 | biostudies-literature | 2017 Sep

REPOSITORIES: biostudies-literature