Emergence of charge density waves and a pseudogap in single-layer TiTe₂.

ABSTRACT: Two-dimensional materials constitute a promising platform for developing nanoscale devices and systems. Their physical properties can be very different from those of the corresponding three-dimensional materials because of extreme quantum confinement and dimensional reduction. Here we report a study of TiTe₂ from the single-layer to the bulk limit. Using angle-resolved photoemission spectroscopy and scanning tunneling microscopy and spectroscopy, we observed the emergence of a (2 × 2) charge density wave order in single-layer TiTe₂ with a transition temperature of 92 ± 3 K. Also observed was a pseudogap of about 28 meV at the Fermi level at 4.2 K. Surprisingly, no charge density wave transitions were observed in two-layer and multi-layer TiTe₂, despite the

SUBMITTER: Chen P 

PROVIDER: S-EPMC5593837 | biostudies-literature | 2017 Sep

REPOSITORIES: biostudies-literature