A one-dimensional bromide-bridged Pt^II/Pt^IV mixed-valence complex with a 2-bromo-ethane-sulfonate counter-ion.

ABSTRACT: The title salt, catena-poly[[[bis-(ethyl-enedi-amine)-platinum(II)]-μ-bromido-[bis(ethyl-enedi-amine)-platinum(IV)]-μ-bromido] tetra-kis-(2-bromo-ethane-sulfon-ate) dihydrate], {[Pt^IIPt^IVBr₂(C₂H₈N₂)₄](C₂H₄BrSO₃)₄·2H₂O} _n , crystallizes in the space group P2₁2₁2. It has a linear chain structure extending parallel to the c axis, composed of square-planar [Pt(en)₂]²⁺ and elongated octa-hedral trans-[PtBr₂(en)₂]²⁺ cations (en is ethyl-enedi-amine) stacked alternately and bridged by the Br atoms. The Pt site of the [Pt^II/IV(en)₂

SUBMITTER: Matsushita N 

PROVIDER: S-EPMC5598828 | biostudies-literature | 2017 Jul

REPOSITORIES: biostudies-literature