Catalytic Behavior of Chromium Oxide Supported on Nanocasting-Prepared Mesoporous Alumina in Dehydrogenation of Propane.

ABSTRACT: Mesoporous alumina with narrow pore size distribution centered in the range of 4.4-5.0 nm and with a specific surface area as high as 270 m²·g-1 was prepared via the nanocasting approach using a CMK-3 carbon replica as a hard template. Based on this support, a series of catalysts containing 1, 5, 10, 20 and 30 wt % of chromium was prepared by incipient wetness impregnation, characterized, and studied in the dehydrogenation of propane to propene (PDH). Cr species in three oxidation states-Cr(III), Cr(V) and Cr(VI)-were found on the oxidized surface of the catalysts. The concentration of these species varied with the total Cr loading. Temperature-programmed reduction (H₂-TPR) and UV-Vis diffuse reflectance spectroscopy (UV-Vis-DRS) studies revealed that Cr(VI) species dominated at the lowest

SUBMITTER: Wegrzyniak A 

PROVIDER: S-EPMC5618360 | biostudies-literature | 2017 Sep

REPOSITORIES: biostudies-literature