The Role of Surface-Bound Dihydropyridine Analogues in Pyridine-Catalyzed CO₂ Reduction over Semiconductor Photoelectrodes.

ABSTRACT: We propose a general reaction mechanism for the pyridine (Py)-catalyzed reduction of CO₂ over GaP(111), CdTe(111), and CuInS₂(112) photoelectrode surfaces. This mechanism proceeds via formation of a surface-bound dihydropyridine (DHP) analogue, which is a newly postulated intermediate in the Py-catalyzed mechanism. Using density functional theory, we calculate the standard reduction potential related to the formation of the DHP analogue, which demonstrates that it is thermodynamically feasible to form this intermediate on all three investigated electrode surfaces under photoelectrochemical conditions. Hydride transfer barriers from the intermediate to CO₂ demonstrate that the surface-bound DHP analogue is as effective at reducing CO₂ to HCOO

SUBMITTER: Senftle TP 

PROVIDER: S-EPMC5620980 | biostudies-literature | 2017 Sep

REPOSITORIES: biostudies-literature