β-D-Arabinosyl 1-C-sulfonic acid.

ABSTRACT: A short synthetic route to β,d-arabinofuranosyl 1-C-sulfonic acid (7), a possible biomimetic for the arabinofuranosyl anomeric phosphate, is described. The furanosyl 1-C-sulfonate was prepared by buffered DMDO oxidation of an S-acetyl-1-thio-β-arabinofuranose derivative. Deprotection under mild conditions allowed isolation of the free sulfonic acid without desulfonylation.

SUBMITTER: Won WS 

PROVIDER: S-EPMC5621591 | biostudies-literature | 2013

REPOSITORIES: biostudies-literature