Direct experimental observation of the molecular J _eff = 3/2 ground state in the lacunar spinel GaTa₄Se₈.

ABSTRACT: Strong spin-orbit coupling lifts the degeneracy of t _2g orbitals in 5d transition-metal systems, leaving a Kramers doublet and quartet with effective angular momentum of J _eff = 1/2 and 3/2, respectively. These spin-orbit entangled states can host exotic quantum phases such as topological Mott state, unconventional superconductivity, and quantum spin liquid. The lacunar spinel GaTa₄Se₈ was theoretically predicted to form the molecular J _eff = 3/2 ground state. Experimental verification of its existence is an important first step to exploring the consequences of the J _eff = 3/2 state. Here, we report direct experimental evidence of the J _eff = 3/2 state in GaTa₄Se₈ by means of excitation spect

SUBMITTER: Jeong MY 

PROVIDER: S-EPMC5627251 | biostudies-literature | 2017 Oct

REPOSITORIES: biostudies-literature