Directed nucleophilic addition of phenoxides to cyclopropenes.

ABSTRACT: The alkali metal-templated addition of aryloxides across the double bond of non-conjugated cyclopropenes is described. High cis-selectivity is achieved through a directing effect of a strategically positioned carboxamide functionality.

SUBMITTER: Yamanushkin P 

PROVIDER: S-EPMC5629095 | biostudies-literature | 2017 Oct

REPOSITORIES: biostudies-literature