Dehydrogenation, disproportionation and transfer hydrogenation reactions of formic acid catalyzed by molybdenum hydride compounds.

ABSTRACT: The cyclopentadienyl molybdenum hydride compounds, CpRMo(PMe3)3-x (CO) x H (CpR = Cp, Cp*; x = 0, 1, 2 or 3), are catalysts for the dehydrogenation of formic acid, with the most active catalysts having the composition CpRMo(PMe3)2(CO)H. The mechanism of the catalytic cycle is proposed to involve (i) protonation of the molybdenum hydride complex, (ii) elimination of H2 and coordination of formate, and (iii) decarboxylation of the formate ligand to regenerate the hydride species. NMR spectroscopy indicates that the nature of the resting state depends on the composition of the catalyst. For example, (i) the resting states for the CpMo(CO)3H and CpMo(PMe3)(CO)2H systems are the hydride complexes themselves, (ii) the resting state for the CpMo(PMe3)3H system is the protonated species [CpMo(PMe3

SUBMITTER: Neary MC 

PROVIDER: S-EPMC5649328 | biostudies-literature | 2015 Mar

REPOSITORIES: biostudies-literature