A heterobimetallic complex featuring a Ti-Co multiple bond and its application to the reductive coupling of ketones to alkenes.

ABSTRACT: To explore metal-metal multiple bonds between first row transition metals, Ti/Co complexes supported by two phosphinoamide ligands have been synthesized and characterized. The Ti metalloligand Cl₂Ti(XylNPⁱPr₂)₂ (1) was treated with CoI₂ under reducing conditions, permitting isolation of the Ti/Co complex [(μ-Cl)Ti(XylNPⁱPr₂)₂CoI]₂ (2). One electron reduction of complex 2 affords ClTi(XylNPⁱPr₂)₂CoPMe₃ (3), which features a metal-metal triple bond and an unprecedentedly short Ti-Co distance of 2.0236(9) Å. This complex is shown to promote the McMurry coupling reaction of aryl ketones into alkenes, with concomitant formatio

SUBMITTER: Wu B 

PROVIDER: S-EPMC5654242 | biostudies-literature | 2015 Mar

REPOSITORIES: biostudies-literature