Mixed-valent, heteroleptic homometallic diketonates as templates for the design of volatile heterometallic precursors.

ABSTRACT: A novel series of mixed-valent, heteroleptic transition metal diketonates that can be utilized as prospective single-source precursors for the low-temperature preparation of oxide materials are reported. The first mixed-valent iron β-diketonates with different FeIII/FeII ratios have been synthesized by applying the mixed-ligand approach. Based on nearly quantitative reaction yields and analysis of iron-oxygen bonds, these compounds were formulated as [FeIII(acac)3][FeII(hfac)2] (1) and [FeII(hfac)2][FeIII(acac)3][FeII(hfac)2] (2). In the above heteroleptic complexes, the Lewis acidic, coordinatively unsaturated FeII centers chelated by two hfac (hexafluoroacetylacetonate) ligands with electron-withdrawing substituents maintain bridging interactions with oxygen atoms of electron-donating ac

SUBMITTER: Lieberman CM 

PROVIDER: S-EPMC5654368 | biostudies-literature | 2015 May

REPOSITORIES: biostudies-literature