Exceptionally long-lived light-emitting electrochemical cells: multiple intra-cation π-stacking interactions in [Ir(C^N)2(N^N)][PF6] emitters.

ABSTRACT: A series of cyclometalated iridium(iii) complexes [Ir(C^N)2(N^N)][PF6] (N^N = 2,2'-bipyridine (1), 6-phenyl-2,2'-bipyridine (2), 4,4'-di-tert-butyl-2,2'-bipyridine (3), 4,4'-di-tert-butyl-6-phenyl-2,2'-bipyridine (4); HC^N = 2-(3-phenyl)phenylpyridine (HPhppy) or 2-(3,5-diphenyl)phenylpyridine (HPh2ppy)) are reported. They have been synthesized using solvento precursors so as to avoid the use of chlorido-dimer intermediates, chloride ion contaminant being detrimental to the performance of [Ir(C^N)2(N^N)][PF6] emitters in light-electrochemical cell (LEC) devices. Single crystal structure determinations and variable temperature solution 1H NMR spectroscopic data confirm that the pendant phenyl domains engage in multiple face-to-face π-interactions within the coordination sphere of the iridiu

SUBMITTER: Bunzli AM 

PROVIDER: S-EPMC5654370 | biostudies-literature | 2015 May

REPOSITORIES: biostudies-literature