Experimental formation enthalpies for intermetallic phases and other inorganic compounds.

ABSTRACT: The standard enthalpy of formation of a compound is the energy associated with the reaction to form the compound from its component elements. The standard enthalpy of formation is a fundamental thermodynamic property that determines its phase stability, which can be coupled with other thermodynamic data to calculate phase diagrams. Calorimetry provides the only direct method by which the standard enthalpy of formation is experimentally measured. However, the measurement is often a time and energy intensive process. We present a dataset of enthalpies of formation measured by high-temperature calorimetry. The phases measured in this dataset include intermetallic compounds with transition metal and rare-earth elements, metal borides, metal carbides, and metallic silicides. These measurements

SUBMITTER: Kim G 

PROVIDER: S-EPMC5654376 | biostudies-literature | 2017 Oct

REPOSITORIES: biostudies-literature