SuFEx-Based Polysulfonate Formation from Ethenesulfonyl Fluoride-Amine Adducts.

ABSTRACT: The SuFEx-based polycondensation between bisalkylsulfonyl fluorides (AA monomers) and bisphenol bis(t-butyldimethylsilyl) ethers (BB monomers) using [Ph₃ P=N-PPh₃ ]⁺ [HF₂ ]^- as the catalyst is described. The AA monomers were prepared via the highly reliable Michael addition of ethenesulfonyl fluoride and amines/anilines while the BB monomers were obtained from silylation of bisphenols by t-butyldimethylsilyl chloride. With these reactions, a remarkable diversity of monomeric building blocks was achieved by exploiting readily available amines, anilines, and bisphenols as starting materials. The SuFEx-based polysulfonate formation reaction exhibited excellent efficiency and functional group tolerance, producing polysulfonates with a vari

SUBMITTER: Wang H 

PROVIDER: S-EPMC5665377 | biostudies-literature | 2017 Sep

REPOSITORIES: biostudies-literature