A nitrogen-base catalyzed generation of organotin(ii) hydride from an organotin trihydride under reductive dihydrogen elimination.

ABSTRACT: Since their first description over a decade ago, organotin(ii) hydrides have been an iconic class of compounds in molecular main group chemistry. Among other approaches they have been accessed from the hydrogenation of distannynes. We herein report their accessibility from the other direction by dehydrogenation of organotin trihydride. On reacting pyridine and amine bases with the bulky substituted organotin trihydride Ar*SnH₃ (Ar* = 2,6-trip₂(C₆H₃)-, trip = 2,4,6-triisopropylphenyl) hydrogen evolution was observed. In case of catalytic amounts of base the dehydro-coupling product diorganodistannane Ar*H₂SnSnH₂Ar* was obtained quantitatively whilst for excessive amounts (>4 eq.) the monomeric base adduct to known Ar*SnH was

SUBMITTER: Sindlinger CP 

PROVIDER: S-EPMC5667502 | biostudies-literature | 2015 Aug

REPOSITORIES: biostudies-literature