Redox reaction induced Ostwald ripening for size- and shape-focusing of palladium nanocrystals.

ABSTRACT: We report here that size- and shape-focusing can be achieved through the well-known Ostwald ripening process to produce high-quality metal nanocrystals (NCs). Using Pd as an example, we show that the addition of small NCs of appropriate sizes could help in modulating the growth of larger NCs and enable excellent control over both the size and shape uniformity of the products. A detailed mechanistic study showed that the self-focusing of Pd NCs relied on a dissolution and regrowth process induced by redox reaction of HCHO. With the assistance of HCHO, injection of small sacrificial nanocrystals (SNCs), with sizes below a critical value, into larger seeds results in the dissolution of the SNCs and subsequent deposition onto the larger ones, thus allowing the formation of monodisperse Pd NCs.

SUBMITTER: Zhang Z 

PROVIDER: S-EPMC5669216 | biostudies-literature | 2015 Sep

REPOSITORIES: biostudies-literature