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Enantioselective Synthesis of Cyclobutenes by Intermolecular [2+2] Cycloaddition with Non-C₂ Symmetric Digold Catalysts.

ABSTRACT: The enantioselective intermolecular gold(I)-catalyzed [2+2] cycloaddition of terminal alkynes and alkenes has been achieved using non-C₂-chiral Josiphos digold(I) complexes as catalysts, by the formation of the monocationic complex. This new approach has been applied to the enantioselective total synthesis of rumphellaone A.

SUBMITTER: Garcia-Morales C

PROVIDER: S-EPMC5679663 | biostudies-literature | 2017 Oct

REPOSITORIES: biostudies-literature

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Dataset Information

Enantioselective Synthesis of Cyclobutenes by Intermolecular [2+2] Cycloaddition with Non-C₂ Symmetric Digold Catalysts.

OmicsDI is part of the ELIXIR infrastructure

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Dataset Information

Enantioselective Synthesis of Cyclobutenes by Intermolecular [2+2] Cycloaddition with Non-C2 Symmetric Digold Catalysts.

OmicsDI is part of the ELIXIR infrastructure

Tweets

Enantioselective Synthesis of Cyclobutenes by Intermolecular [2+2] Cycloaddition with Non-C₂ Symmetric Digold Catalysts.