Crystal structure of poly[di-aqua-bis-(μ5-benzene-1,3-di-carboxyl-ato)(N,N-di-methyl-formamide)-cadmium(II)disodium(I)].

ABSTRACT: The title compound, [CdNa2(C8H4O4)2(C3H7NO)(H2O)2] n or [CdNa2(1,3-bdc)2(DMF)(H2O)2] n , is a new CdII-NaI heterobimetallic coordination polymer. The asymmetric unit consists of one CdII atom, two NaI atoms, two 1,3-bdc ligands, two coordinated water mol-ecules and one coordinated DMF mol-ecule. The CdII atom exhibits a seven-coordinate geometry, while the NaI atoms can be considered to be penta-coordinate. The metal ions and their symmetry-related equivalents are connected via chelating-bridging carboxyl-ate groups of the 1,3-bdc ligands to generate a three-dimensional framework. In the crystal, there are classical O-H⋯O hydrogen bonds involving the coordinated water mol-ecules and the 1,3-bdc carboxyl-ate groups and π-π stacking between the benzene rings of the 1,3-bdc ligands present wi

SUBMITTER: Sangsawang M 

PROVIDER: S-EPMC5683472 | biostudies-literature | 2017 Nov

REPOSITORIES: biostudies-literature