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Synthesis and crystal structure of bis-(1H-benzo[d][1,2,3]triazole-κN²){2,2'-[N-(phenyl-phospho-r-yl-methyl-κO)aza-nedi-yl]di-acetato-κ³O,N,O'}cobalt(II)-1H-benzo[d][1,2,3]triazole (1/1).

ABSTRACT: In the title compound, [Co(C₁₁H₁₂NO₆P)(C₆H₅N₃)₂]·C₆H₅N₃, the 2,2'-[N-(phenyl-phospho-rylmethyl-κO)aza-nedi-yl]di-acetate dianion N,O,O',O''-chelates the Co^II cation and two 1H-benzo[d][1,2,3]triazole mol-ecules coordinate to the Co^II cation to complete the slightly distorted octa-hedral coordination. In the crystal, classical O-H⋯O, N-H⋯O hydrogen bonds and weak C-H⋯N hydrogen bonds link the mol-ecules into a three-dimensional supra-molecular architecture. π-π stacking between the triazole and benzene rings and between the benzene rings is also observed in the crystal.

SUBMITTER: Du CJ

PROVIDER: S-EPMC5683495 | biostudies-literature | 2017 Nov

REPOSITORIES: biostudies-literature

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Synthesis and crystal structure of bis-(1H-benzo[d][1,2,3]triazole-κN²){2,2'-[N-(phenyl-phospho-r-yl-methyl-κO)aza-nedi-yl]di-acetato-κ³O,N,O'}cobalt(II)-1H-benzo[d][1,2,3]triazole (1/1).

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Dataset Information

Synthesis and crystal structure of bis-(1H-benzo[d][1,2,3]triazole-κN2){2,2'-[N-(phenyl-phospho-r-yl-methyl-κO)aza-nedi-yl]di-acetato-κ3O,N,O'}cobalt(II)-1H-benzo[d][1,2,3]triazole (1/1).

OmicsDI is part of the ELIXIR infrastructure

Tweets

Synthesis and crystal structure of bis-(1H-benzo[d][1,2,3]triazole-κN²){2,2'-[N-(phenyl-phospho-r-yl-methyl-κO)aza-nedi-yl]di-acetato-κ³O,N,O'}cobalt(II)-1H-benzo[d][1,2,3]triazole (1/1).