Unknown

Dataset Information

0

Synthesis and crystal structure of a two-dimensional CoII coordination polymer: poly[(μ3-3-carb-oxy-benzoato)[μ2-5-(pyridin-4-yl)-1H,2'H-3,3'-bi[1,2,4-triazole]]cobalt(II)].

ABSTRACT: In the title compound, [Co(C8H5O4)(C9H6N7)] n , the divalent CoII atom is six-coordinated to three N atoms from two symmetrical 5-(pyridin-4-yl)-1H,2'H-3,3'-bi[1,2,4-triazole] (H2pyttz) ligands and three O atoms from three symmetrical 3-carb-oxy-benzoate (Hbdic) ligands, leading to a distorted {CoN3O3} octa-hedral coordination environment. Two CoII cations are linked by four bridging carboxyl-ate groups to generate a dinuclear [Co2(CO2)4] unit. The dinuclear units are further connected into a chain along [010] via the Hbdic ligands. The other infinite chain, along [100], is formed through the H2pyttz ligands. Finally, the two kinds of chains are cross-linked, by sharing the CoII cations, into a two-dimensional network. In the crystal, adjacent layers are further linked by O-H⋯N hydrogen bonds into a three-dimensional framework.

SUBMITTER: Du CJ 

PROVIDER: S-EPMC5683512 | biostudies-literature | 2017 Nov

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Synthesis and crystal structure of a two-dimensional Co<sup>II</sup> coordination polymer: poly[(μ<sub>3</sub>-3-carb-oxy-benzoato)[μ<sub>2</sub>-5-(pyridin-4-yl)-1<i>H</i>,2'<i>H</i>-3,3'-bi[1,2,4-triazole]]cobalt(II)].

Du Chao-Jun CJ   Zhao Xiao-Na XN   Chen Bao-Yong BY  

Acta crystallographica. Section E, Crystallographic communications 20171027 Pt 11

In the title compound, [Co(C<sub>8</sub>H<sub>5</sub>O<sub>4</sub>)(C<sub>9</sub>H<sub>6</sub>N<sub>7</sub>)] <sub><i>n</i></sub> , the divalent Co<sup>II</sup> atom is six-coordinated to three N atoms from two symmetrical 5-(pyridin-4-yl)-1<i>H</i>,2'<i>H</i>-3,3'-bi[1,2,4-triazole] (H<sub>2</sub>pyttz) ligands and three O atoms from three symmetrical 3-carb-oxy-benzoate (Hbdic) ligands, leading to a distorted {CoN<sub>3</sub>O<sub>3</sub>} octa-hedral coordination environment. Two Co<sup>II</s  ...[more]

Similar Datasets

Unknown 5-(Pyridin-2-yl)-3,3'-bi(1H-1,2,4-triazole).
| S-EPMC3213486 | biostudies-literature
Unknown Poly[(3-nitro-benzoato)(μ(3)-1,2,4-triazolato)cobalt(II)].
| S-EPMC2968154 | biostudies-literature
Unknown Poly[[μ-1,4-bis-(pyridin-4-ylmeth-yl)piperazine]bis-[μ<sub>3</sub>-4-(2-carboxyl-atoeth-yl)benzoato]dicopper(II)].
| S-EPMC10483545 | biostudies-literature
Unknown Poly[dibromidobis[μ-1-(pyridin-4-ylmeth-yl)-1H-1,2,4-triazole-κN:N']cadmium].
| S-EPMC3051776 | biostudies-literature
Unknown μ-1,4-Bis(pyridin-4-ylmeth-yl)piperazine-κN:N'-bis-[aqua-bis-(3-bromo-5-carb-oxy-benzoato-κO)copper(II)].
| S-EPMC3274888 | biostudies-literature
Unknown Crystal structure of poly[tetra-μ-chlorido-tetra-chlorido-bis-(μ<sub>3</sub>-4,4'-bi-1,2,4-triazole-κ<sup>3</sup> <i>N</i> <sup>1</sup>:<i>N</i> <sup>2</sup>:<i>N</i> <sup>1'</sup>)(μ-4,4'-bi-1,2,4-triazole-κ<sup>3</sup> <i>N</i> <sup>1</sup>:<i>N</i> <sup>1'</sup>)tetra-copper(II)].
| S-EPMC6658958 | biostudies-literature
Unknown [Hydrogen bis-(1,2,4-triazole)] 1,2,4-triazolium bis-(3-carb-oxy-4-hy-droxy-benzene-sulfonate) 1,2,4-triazole disolvate.
| S-EPMC3007327 | biostudies-literature
Unknown catena-Poly[[dibromidozinc(II)]-μ-4-(3-pyrid-yl)-4H-1,2,4-triazole].
| S-EPMC3007524 | biostudies-literature
Unknown catena-Poly[[triaqua-zinc(II)]-μ-1H-1,2,4-triazole-3,5-dicarboxyl-ato].
| S-EPMC2960531 | biostudies-literature
Unknown Poly[dichloridobis[μ-1-(4-pyridyl-meth-yl)-1,2,4-triazole]cadmium(II)].
| S-EPMC2983120 | biostudies-literature