Comparing postdeposition reactions of electrons and radicals with Pt nanostructures created by focused electron beam induced deposition.

ABSTRACT: The ability of electrons and atomic hydrogen (AH) to remove residual chlorine from PtCl₂ deposits created from cis-Pt(CO)₂Cl₂ by focused electron beam induced deposition (FEBID) is evaluated. Auger electron spectroscopy (AES) and energy-dispersive X-ray spectroscopy (EDS) measurements as well as thermodynamics calculations support the idea that electrons can remove chlorine from PtCl₂ structures via an electron-stimulated desorption (ESD) process. It was found that the effectiveness of electrons to purify deposits greater than a few nanometers in height is compromised by the limited escape depth of the chloride ions generated in the purification step. In contrast, chlorine atoms can be efficiently and completely removed from PtCl₂

SUBMITTER: Spencer JA 

PROVIDER: S-EPMC5704761 | biostudies-literature | 2017

REPOSITORIES: biostudies-literature