Preorganized Ag^I Bimetallic Precursor with Labile Diphosphorus Ligands for a Programmed Synthesis of Organometallic-Organic Hybrid Polymers.

ABSTRACT: An Ag^I dimer capped with labile organometallic diphosphorus ligands [Cp₂ Mo₂ (CO)₄ (η² -P₂ )] (Cp=C₅ H₅ ) acts as a highly pre-organized molecular precursor to direct the construction of 1D or 2D, and 3D organometallic-organic hybrid coordination polymers upon reaction with ditopic pyridine-based linkers. The formation of the supramolecular aggregates can be controlled by the stoichiometry of the organic molecules, and the mechanism is supported by DFT calculations.

SUBMITTER: Moussa ME 

PROVIDER: S-EPMC5708272 | biostudies-literature | 2017 Nov

REPOSITORIES: biostudies-literature