Hydrodenitrogenation of pyridines and quinolines at a multinuclear titanium hydride framework.

ABSTRACT: Investigation of the hydrodenitrogenation (HDN) of aromatic N-heterocycles such as pyridines and quinolines at the molecular level is of fundamental interest and practical importance, as this transformation is essential in the industrial petroleum refining on solid catalysts. Here, we report the HDN of pyridines and quinolines by a molecular trinuclear titanium polyhydride complex. Experimental and computational studies reveal that the denitrogenation of a pyridine or quinoline ring is easier than the ring-opening reaction at the trinuclear titanium hydride framework, which is in sharp contrast with what has been reported previously. Hydrolysis of the pyridine-derived nitrogen-free hydrocarbon skeleton at the titanium framework with H2O leads to recyclization to afford cyclopentadiene with

SUBMITTER: Hu S 

PROVIDER: S-EPMC5709410 | biostudies-literature | 2017 Nov

REPOSITORIES: biostudies-literature