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Crystal structure of mer-tris-{2,6-di-fluoro-3-[5-(2-fluoro-phen-yl)pyridin-2-yl-κN]pyridin-4-yl-κC⁴}iridium(III) di-chloro-methane hemisolvate n-hexane hemisolvate.

ABSTRACT: The asymmetric unit of the title compound, [Ir(C₁₇H₁₁F₂N₂)₃]·0.5CH₃(CH₂)₄CH₃·0.5CH₂Cl₂, comprises one Ir^III atom, three 2,6-di-fluoro-3-[5-(2-fluoro-phen-yl)pyridin-2-yl]pyridin-4-yl ligands and half each of an n-hexane and a di-chloro-methane solvent mol-ecule located about crystallographic inversion centres. The Ir^III atom displays a distorted octa-hedral coordination geometry, having three C,N-chelating 2,6-di-fluoro-3-[5-(2-fluoro-phen-yl)pyridin-2-yl]pyridin-4-yl ligands arranged in a meridional manner. The Ir^III ion lies almost in the equatorial plane [deviation = 0.0069 (15) Å]. The average distance [2.041 (3)

SUBMITTER: Kang Y

PROVIDER: S-EPMC5730259 | biostudies-literature | 2017 Dec

REPOSITORIES: biostudies-literature

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Crystal structure of mer-tris-{2,6-di-fluoro-3-[5-(2-fluoro-phen-yl)pyridin-2-yl-κN]pyridin-4-yl-κC⁴}iridium(III) di-chloro-methane hemisolvate n-hexane hemisolvate.

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Crystal structure of mer-tris-{2,6-di-fluoro-3-[5-(2-fluoro-phen-yl)pyridin-2-yl-κN]pyridin-4-yl-κC4}iridium(III) di-chloro-methane hemisolvate n-hexane hemisolvate.

OmicsDI is part of the ELIXIR infrastructure

Tweets

Crystal structure of mer-tris-{2,6-di-fluoro-3-[5-(2-fluoro-phen-yl)pyridin-2-yl-κN]pyridin-4-yl-κC⁴}iridium(III) di-chloro-methane hemisolvate n-hexane hemisolvate.