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Crystal structure of bis-{μ₂-2,2'-[(4,10-dimethyl-1,4,7,10-tetra-aza-cyclo-dodecane-1,7-di-yl)bis(meth-yl-ene)]bis-(4-oxo-4H-pyran-3-olato)}dicobalt-calcium bis-(perchlorate) 1.36-hydrate.

ABSTRACT: The title compound, [CaCo₂(C₂₂H₃₀N₄O₆)₂](ClO₄)₂·1.36H₂O or {Ca[Co(H_-2L1)]₂}·2ClO₄·1.36H₂O {where L1 is 4,10-bis-[(3-hy-droxy-4-pyron-2-yl)meth-yl]-1,7-dimethyl-1,4,7,10-tetra-aza-cyclo-dodecane}, is a trinuclear complex whose asymmetric unit comprises a quarter of the {Ca[Co(H_-2L1)]₂}²⁺ trinuclear complex, half of a perchlorate ion and 0.34-water mol-ecules. In the neutral [Co(H_-2L1)] moiety, the cobalt ion is hexa-coordinated in a trigonal-prismatic fashion by the surrounding N₄O₂ donor set. A Ca²⁺ cation holds together two neutral [Co(H_-2<

SUBMITTER: Rossi P

PROVIDER: S-EPMC5730261 | biostudies-literature | 2017 Dec

REPOSITORIES: biostudies-literature

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Crystal structure of bis-{μ₂-2,2'-[(4,10-dimethyl-1,4,7,10-tetra-aza-cyclo-dodecane-1,7-di-yl)bis(meth-yl-ene)]bis-(4-oxo-4H-pyran-3-olato)}dicobalt-calcium bis-(perchlorate) 1.36-hydrate.

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Dataset Information

Crystal structure of bis-{μ2-2,2'-[(4,10-dimethyl-1,4,7,10-tetra-aza-cyclo-dodecane-1,7-di-yl)bis(meth-yl-ene)]bis-(4-oxo-4H-pyran-3-olato)}dicobalt-calcium bis-(perchlorate) 1.36-hydrate.

OmicsDI is part of the ELIXIR infrastructure

Tweets

Crystal structure of bis-{μ₂-2,2'-[(4,10-dimethyl-1,4,7,10-tetra-aza-cyclo-dodecane-1,7-di-yl)bis(meth-yl-ene)]bis-(4-oxo-4H-pyran-3-olato)}dicobalt-calcium bis-(perchlorate) 1.36-hydrate.