Bis(3,5-dimeth-oxy-2-{[2-(pyridin-2-yl)ethyl-imino-κN]-meth-yl}phenolato-κO)bis-(dimethyl sulfoxide)-manganese(III) perchlorate methanol 0.774-solvate.

ABSTRACT: The title compound, [Mn(C₁₆H₁₇N₂O₃)₂(C₂H₆OS)₂]ClO₄·0.774CH₃OH, comprises a central octa-hedrally coordinated Mn^III cation, with two bidentate Schiff base ligands occupying the equatorial positions and two dimethyl sulfoxide (DMSO) ligands occupying the axial positions. There are two independant cations in the asymmetric unit, with the Mn^III atoms of both cations being positioned on crystallographic centers of inversion. The perchlorate anion is disordered over two equivalent conformations, with occupancies of 0.744 (3) and 0.226 (3). In addition, there is a methanol solvent mol-ecule in the crystal lattice that is too close to the minor component of the perchl

SUBMITTER: Egekenze R 

PROVIDER: S-EPMC5730299 | biostudies-literature | 2017 Oct

REPOSITORIES: biostudies-literature