Aqua-chlorido-(2-{[6-(di-methyl-amino)-pyrimidin-4-yl]sulfan-yl}pyrimidine-4,6-di-amine)-copper(II) chloride hydrate.

ABSTRACT: A copper(II) complex of the non-symmetric bidentate ligand 2-{[6-(di-methyl-amino)-pyrimidin-4-yl]sulfan-yl}pyrimidine-4,6-di-amine (L1) is reported. The single-crystal X-ray structure of aqua-[aqua/chlorido-(0.49/0.51)](2-{[6-(di-methyl-amino)-pyrimidin-4-yl]sulfan-yl}pyrimidine-4,6-di-amine)-copper(II) 0.49-chloride 1.51-hydrate, [CuCl_1.51(C₁₀H₁₃N₇S)(H₂O)_1.49]Cl_0.49·1.51H₂O or [(L1)Cl_1.51(H₂O)_1.49Cu]0.49Cl·1.51H₂O, exhibits distorted square-pyramidal geometry around the metal centre, with disorder in the axial position, occupied by chloride or water. The six-membered metal-chelate ring is in a boat conformation, and short inter-molecular S⋯S in

SUBMITTER: Moyaert TE 

PROVIDER: S-EPMC5730312 | biostudies-literature | 2017 Oct

REPOSITORIES: biostudies-literature