Dataset Information

Crystal structure of an Ag^I inter-calation compound: catena-poly[[silver(I)-μ-N-(pyridin-3-ylmeth-yl)pyridin-3-amine-κ²N:N'] hexa-fluorido-phosphate aceto-nitrile disolvate].

ABSTRACT: The asymmetric unit in the title compound, [Ag(C₁₁H₁₁N₃)]PF₆·2CH₃CN or {[AgL]·PF₆·2CH₃CN} _n , L = N-(pyridin-3-ylmeth-yl)pyridin-3-amine, comprises one Ag^I atom, one L ligand, two aceto-nitrile solvent mol-ecules and one PF₆^- anion disordered over two orientations in a 0.567 (11):0.433 (11) ratio. Each Ag^I atom is coordinated by two pyridine N atoms from two L ligands in a slightly distorted linear coordination geometry [N-Ag-N = 170.55 (8)°]. Each L ligand bridges two Ag^I ions, resulting in the formation of a zigzag chain propagating along the [101] direction. In the crystal, Ag⋯Ag contacts [3.3023 (

SUBMITTER: Moon SH

PROVIDER: S-EPMC5730314 | biostudies-literature | 2017 Oct

REPOSITORIES: biostudies-literature

ACCESS DATA

Dataset Information

Crystal structure of an Ag^I inter-calation compound: catena-poly[[silver(I)-μ-N-(pyridin-3-ylmeth-yl)pyridin-3-amine-κ²N:N'] hexa-fluorido-phosphate aceto-nitrile disolvate].

OmicsDI is part of the ELIXIR infrastructure

Tweets

Dataset Information

Crystal structure of an AgI inter-calation compound: catena-poly[[silver(I)-μ-N-(pyridin-3-ylmeth-yl)pyridin-3-amine-κ2N:N'] hexa-fluorido-phosphate aceto-nitrile disolvate].

OmicsDI is part of the ELIXIR infrastructure

Tweets

Crystal structure of an Ag^I inter-calation compound: catena-poly[[silver(I)-μ-N-(pyridin-3-ylmeth-yl)pyridin-3-amine-κ²N:N'] hexa-fluorido-phosphate aceto-nitrile disolvate].