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N,N',N'' versus N,N',O imine-containing coordination motifs: ligand-directed synthesis of mononuclear and binuclear Cu^II compounds.

ABSTRACT: It is demonstrated here that tridentate imine ligands can control the nuclearity of copper(II) complexes based on the donor atoms present in the ligand. The N,N',N''-donating imine ligand led to a mononuclear compound, namely di-chlorido-[N,N-dimethyl-N'-(pyridin-2-yl-methyl-idene)ethane-1,2-di-amine]copper(II) monohydrate, [CuCl₂(C₁₀H₁₅N₃)]·H₂O, 1, while the N,N',O-donating imine ligand produced a binuclear metal complex, namely μ₂-chlorido-di-chlorido-(μ₂-2-{[2-(di-methyl-amino)-ethyl]imino-methyl}phenolato)(N,N-dimethyl-ethylene-di-amine)-dicopper(II) 0.11-hydrate, [Cu₂(C₁₁H₁₅N₂O)Cl

SUBMITTER: Ferraz de Paiva RE

PROVIDER: S-EPMC5730319 | biostudies-literature | 2017 Oct

REPOSITORIES: biostudies-literature

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N,N',N'' versus N,N',O imine-containing coordination motifs: ligand-directed synthesis of mononuclear and binuclear Cu^II compounds.

OmicsDI is part of the ELIXIR infrastructure

Tweets

Dataset Information

N,N',N'' versus N,N',O imine-containing coordination motifs: ligand-directed synthesis of mononuclear and binuclear CuII compounds.

OmicsDI is part of the ELIXIR infrastructure

Tweets

N,N',N'' versus N,N',O imine-containing coordination motifs: ligand-directed synthesis of mononuclear and binuclear Cu^II compounds.