Superoxide stability for reversible Na-O₂ electrochemistry.

ABSTRACT: Stabilizing superoxide (O₂^-) is one of the key issues of sodium-air batteries because the superoxide-based discharge product (NaO₂) is more reversibly oxidized to oxygen when compared with peroxide (O₂^2-) and oxide (O^2-). Reversibly outstanding performances of sodium-oxygen batteries have been realized with the superoxide discharge product (NaO₂) even if sodium peroxide (Na₂O₂) have been also known as the discharge products. Here we report that the Lewis basicity of anions of sodium salts as well as solvent molecules, both quantitatively represented by donor numbers (DNs), determines the superoxide stability and resultantly the reversibility of sodium-oxygen batteries. A DN map of superoxide

SUBMITTER: Dilimon VS 

PROVIDER: S-EPMC5732307 | biostudies-literature | 2017 Dec

REPOSITORIES: biostudies-literature