Ontology highlight
ABSTRACT:
SUBMITTER: Lamb CJC
PROVIDER: S-EPMC5767738 | biostudies-literature | 2017 Dec
REPOSITORIES: biostudies-literature
Lamb Claire J C CJC Nderitu Bryan G BG McMurdo Gemma G Tobin John M JM Vilela Filipe F Lee Ai-Lan AL
Chemistry (Weinheim an der Bergstrasse, Germany) 20171130 72
A Pd<sup>II</sup> catalyst system has been used to successfully catalyse two mechanistically distinct reactions in a one-pot procedure: dehydrogenation of 2,2-disubstituted cyclopentane-1,3-diones and the subsequent oxidative Heck coupling. This auto-tandem catalytic reaction is applicable to both batch and continuous flow processes, with the latter being the first example of a tandem aerobic dehydrogenation/oxidative Heck in flow. In addition, a telescoped reaction involving enantioselective de ...[more]