Bis{μ-2,2'-[(3,4-di-thia-hexane-1,6-di-yl)bis-(nitrilo-methanylyl-idene)]bis-(4-bromo-phenolato)-κ⁴O,N,N',O'}dicopper(II).

ABSTRACT: The crystal structure of the title compound, [Cu₂(C₁₈H₁₂Br₂N₄O₂S₂)₂], consists of binuclear complex units which lie across inversion centres and are connected by weak Cu-O coordination bonds forming chains along the b axis. The Cu^II ion is five-coordinated by two N atoms and two O atoms of the chelating ligand and one symmetry-related O atom forming a square-pyramidal coordination geometry. In the crystal, short S⋯Br contacts connect neighbouring chains into a two-dimensional network parallel to (101).

SUBMITTER: Rusanova JA 

PROVIDER: S-EPMC5778481 | biostudies-literature | 2018 Jan

REPOSITORIES: biostudies-literature