Nickel-Catalyzed Stereoselective Arylboration of Unactivated Alkenes.

ABSTRACT: A Ni-catalyzed method for arylboration is disclosed. The method allows for highly stereoselective arylboration of unactivated alkenes. The reactions utilize a simple Ni-catalyst and work with a broad range of alkenes and aryl bromides. The products represent useful intermediates for chemical synthesis due to the versatility of the C-B bond. Preliminary mechanistic details of the method are also disclosed.

SUBMITTER: Logan KM 

PROVIDER: S-EPMC5778876 | biostudies-literature | 2018 Jan

REPOSITORIES: biostudies-literature