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Ultrathin silicon oxynitride layer on GaN for dangling-bond-free GaN/insulator interface.

ABSTRACT: Despite the scientific and technological importance of removing interface dangling bonds, even an ideal model of a dangling-bond-free interface between GaN and an insulator has not been known. The formation of an atomically thin ordered buffer layer between crystalline GaN and amorphous SiO₂ would be a key to synthesize a dangling-bond-free GaN/SiO₂ interface. Here, we predict that a silicon oxynitride (Si₄O₅N₃) layer can epitaxially grow on a GaN(0001) surface without creating dangling bonds at the interface. Our ab initio calculations show that the GaN/Si₄O₅N₃ structure is more stable than silicon-oxide-terminated GaN(0001) surfaces. The electronic properties of the GaN/Si₄O₅N₃ structure can be tuned by modifying the chemical components near the interface. We also propose a possible approach to experimentally synthesize the GaN/Si₄O₅N₃ structure.

SUBMITTER: Nishio K

PROVIDER: S-EPMC5780416 | biostudies-literature | 2018 Jan

REPOSITORIES: biostudies-literature

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Ultrathin silicon oxynitride layer on GaN for dangling-bond-free GaN/insulator interface.

Nishio Kengo K Yayama Tomoe T Miyazaki Takehide T Taoka Noriyuki N Shimizu Mitsuaki M

Scientific reports 20180123 1

Despite the scientific and technological importance of removing interface dangling bonds, even an ideal model of a dangling-bond-free interface between GaN and an insulator has not been known. The formation of an atomically thin ordered buffer layer between crystalline GaN and amorphous SiO2 would be a key to synthesize a dangling-bond-free GaN/SiO2 interface. Here, we predict that a silicon oxynitride (Si4O5N3) layer can epitaxially grow on ...[more]

PMID: 29362443

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