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Reactivity of uranium(iii) with H₂E (E = S, Se, Te): synthesis of a series of mononuclear and dinuclear uranium(iv) hydrochalcogenido complexes.

ABSTRACT: We report the syntheses, electronic properties, and molecular structures of a series of mono- and dinuclear uranium(iv) hydrochalcogenido complexes supported by the sterically demanding but very flexible, single N-anchored tris(aryloxide) ligand (^AdArO)₃N)^3-. The mononuclear complexes [((^AdArO)₃N)U(DME)(EH)] (E = S, Se, Te) can be obtained from the reaction of the uranium(iii) starting material [((^AdArO)₃N)U^III(DME)] in DME via reduction of H₂E and the elimination of 0.5 equivalents of H₂. The dinuclear complexes [{((^AdArO)₃N)U}₂(μ-EH)₂] can be obtained by dissolving their mononuclear counterparts in non-coordinating solvents such

SUBMITTER: Franke SM

PROVIDER: S-EPMC5811169 | biostudies-literature | 2015 Jan

REPOSITORIES: biostudies-literature

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Reactivity of uranium(iii) with H₂E (E = S, Se, Te): synthesis of a series of mononuclear and dinuclear uranium(iv) hydrochalcogenido complexes.

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Reactivity of uranium(iii) with H2E (E = S, Se, Te): synthesis of a series of mononuclear and dinuclear uranium(iv) hydrochalcogenido complexes.

OmicsDI is part of the ELIXIR infrastructure

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Reactivity of uranium(iii) with H₂E (E = S, Se, Te): synthesis of a series of mononuclear and dinuclear uranium(iv) hydrochalcogenido complexes.