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Palladium-Catalyzed Atom-Transfer Radical Cyclization at Remote Unactivated C(sp3 )-H Sites: Hydrogen-Atom Transfer of Hybrid Vinyl Palladium Radical Intermediates.


ABSTRACT: A novel mild, visible-light-induced palladium-catalyzed hydrogen atom translocation/atom-transfer radical cyclization (HAT/ATRC) cascade has been developed. This protocol involves a 1,5-HAT process of previously unknown hybrid vinyl palladium radical intermediates, thus leading to iodomethyl carbo- and heterocyclic structures.

SUBMITTER: Ratushnyy M 

PROVIDER: S-EPMC5829020 | biostudies-literature | 2018 Mar

REPOSITORIES: biostudies-literature

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Palladium-Catalyzed Atom-Transfer Radical Cyclization at Remote Unactivated C(sp<sup>3</sup> )-H Sites: Hydrogen-Atom Transfer of Hybrid Vinyl Palladium Radical Intermediates.

Ratushnyy Maxim M   Parasram Marvin M   Wang Yang Y   Gevorgyan Vladimir V  

Angewandte Chemie (International ed. in English) 20180206 10


A novel mild, visible-light-induced palladium-catalyzed hydrogen atom translocation/atom-transfer radical cyclization (HAT/ATRC) cascade has been developed. This protocol involves a 1,5-HAT process of previously unknown hybrid vinyl palladium radical intermediates, thus leading to iodomethyl carbo- and heterocyclic structures. ...[more]

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